Solubility and Solubility-Limiting Solid Phase in M(IV)-OH-Dicarboxylate Ternary Aqueous System

スポンサーリンク

概要

• 論文の詳細を見る

• The solubilities of thorium and zirconium in the presence of several dicarboxylic acids were investigated as functions of the hydrogen ion concentration (pHc). In the presence of succinic, glutaric, and adipic acids, few Th colloidal species larger than 2 nm were observed, and the apparent solubility appeared to be controlled by thorium-dicarboxylate solid phases. The Th solubility in the presence of fumaric (trans-butenedioic) acid was similar to that in the presence of succinic (butanedioic) acid, whereas no solid phase was observed under pHc 4 in the presence of maleic (cis-butenedioic) acid. In the presence of succinic and glutaric acids, the contributions of Zr colloidal species to the apparent solubility were observed, possibly due to the stronger hydrolysis reaction than that of Th. The solubility product values of Th and Zr dicarboxylates were determined from the analysis of the solubility data.

• 2011-07-01

著者

• MORIYAMA Hirotake

  Research Reactor Institute, Kyoto University

• TAKAGI Ikuji

  Department of Nuclear Engineering, Kyoto University

• Takagi Ikuji

  Dep. Of Nuclear Engineering Kyoto Univ.

• Takagi I

  Kyoto Univ. Kyoto

• Takagi Ikuji

  Department Of Nuclear Engineering Kyoto University

• MORIYAMA Hirotake

  Department of Nuclear Engineering, Kyoto University

• Moriyama Hirotake

  Dep. Of Nuclear Engineering Kyoto Univ.

• Moriyama Hirotake

  Research Reactor Institute Kyoto University

• KOBAYASHI Taishi

  Department of Nuclear Engineering, Kyoto University

• Kawasaki Toru

  Department Of Nuclear Engineering Kyoto University

• KOBAYASHI Taishi

  Research Reactor Institute, Kyoto University

• Sasaki Takayuki

  Department Of Nuclear Engineering Kyoto University

• Sasaki Takayuki

  Department Of Biology Faculty Of Science Niigata University

関連論文

• Simultaneous Measurement of Prompt Neutrons and Fission Fragments for ^Pu(n_, f)
• Measurement of ^Al in Terrestrial Silicate Rock, Revisited
• Tritium Release from Improved Ceramic Tritium Breeder with Catalytic Function
• A Simple Model for Hydrogen Re-distribution in Zirconium-lined Fuel Claddings
• 金(III)面上に形成したリン脂質/アルカンチオール二分子膜およびリン脂質単分子膜に対するホスホリパーゼCの加水分解活性
• Genetically engineered Bifidobacterium longum for tumor-targeting enzyme-prodrug therapy of autochthonous mammary tumors in rats
• Cloned Cytosine Deaminase Gene Expression of Bifidobacterium longum and Application to Enzyme/Pro-drug Therapy of Hypoxic Solid Tumors(Biochemistry & Molecular Biology)
• Detection of Polynuclear Zirconium Hydroxide Species in Aqueous Solution by Desktop ESI-MS
• Thermodynamic Properties of Lanthanides and Actinides for Reductive Extraction of Minor Actinides
• Solubility of Thorium(IV) in the Presence of Oxalic and Malonic Acids
• Zirconium Solubility in Ternary Aqueous System of Zr (IV) -OH-Carboxylates
• Hydrolysis Constant and Coordination Geometry of Zirconium(IV)
• Discrete Fragment Model for Complex Formation of Europium(III) with Humic Acid
• Analysis of Sorption Behavior of Cesium Ion on Mineral Components of Granite
• Solubility of Zirconium(IV) Hydrous Oxides
• Measurement and Analysis of Formation Constants of Europium with Carboxylates
• Systematics of Hydrolysis Constants of Tetravalent Actinide Ions
• Simulated Waste Glass Corrosion in Humic Acid Solution using Rutherford Backscattering Spectrometry
• Analysis of Adsorption Behavior of Cations onto Quartz Surface by Electrical Double-layer Model
• Analysis of Adsorption Behavior of Cesium onto Quartz Using Electrical Double Layer Model
• Production of Pure ^Pu Tracer for the Assessment of Plutonium in the Environment
• Incommensurate Magnetic Structure of the Heavy Fermion Antiferromagnet Ce_7Ni_3 : Condensed Matter: Electronic Properties, etc.
• Clinical Pharmacokinetics of Mycophenolate Mofetil in Japanese Renal Transplant Recipients : a Retrospective Cohort Study in a Single Center(Biopharmacy)
• Solubility and Solubility-Limiting Solid Phase in M(IV)-OH-Dicarboxylate Ternary Aqueous System
• Analysis of Sorption Behavior of Cesium and Iodide Ions on Pumice Tuff
• Exogeneous Cytosine Deaminase Gene Expression in Bifidobacterium breve I-53-8w for Tumor-Targeting Enzyme/Prodrug Therapy
• Strong Enhancement of Recombinant Cytosine Deaminase Activity in Bifidobacterium longum for Tumor-Targeting Enzyme/Prodrug Therapy
• Solubility Product of Hexavalent Uranium Hydrous Oxide
• Reductive Extraction of Actinides and Lanthanides from Molten Chloride Salt into Liquid Zinc
• Carbonic anhydrase is induced prior to arylsulfatase under the simultaneous deprivation of inorganic carbon and sulfate in Chlamydomonas reinhardtii (Volvocales, Chlorophyta)
• Equilibrium Distributions of Actinides and Lanthanides in Molten Salt and Liquid Metal Binary Phase Systems
• Solubility and Solubility-Limiting Solid Phase in M(IV)-OH-Dicarboxylate Ternary Aqueous System
• Isotope Effects of Hafnium in Solvent Extraction Using Crown Ethers
• Analysis of Sorption Behavior of Cesium and Iodide Ions on Pumice Tuff
• An Application of Actinide Elements for a Redox Flow Battery
• Formation Constants of Eu(III)-Carboxylates Determined by Ion-selective Liquid Membrane Electrode
• Electromotive force measurement of lanthanides in liquid lead
• Irradiation effects on thermal diffusivity and positron annihilation lifetime in ceramics induced by neutron and 30MeV electron
• Migration of radionuclide through two-layered geologic media.

もっと見る 閉じる

スポンサーリンク