B/E Constant Linked Scan Fast Atom Bombardment Analysis of a New Type of Glycosyl Phosphosphingolipid Isolated from Edible Fungi (Mushroom)
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概要
- 論文の詳細を見る
The structures of new type of glycosyl phosphosphingolipids (1-4) isolated from Hypsizigus marmoreus (Bunashimeji, a mushroom) were determined by B/E constant linked scan fast atom bombardment (FAB) mass spectrometry. Each molecular species has common to a phytosphingosine (4-hydroxy-C18-sphinganine) in the long-chain base, phosphodihexose group, and a fatty acid of the difference of carbon numbers. The alkyl chains of fatty acids are determined to be 2-hydroxyoctadecane, 2-hydroxyhexadecane, 2-hydroxytetracosane, and 2-hydroxydocosane for 1-4, respectively. The ions of m/z 421 and 720 in the negative ion mode analyses are assigned to be characteristic of a phosphodihexose and a phytosphingosine containing phosphodihexose, respectively.
- 日本質量分析学会の論文
- 1995-04-30
著者
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OKAMOTO Tadashi
Department of Health Sciences and Social Pharmacy, Faculty of Pharmaceutical Sciences, Kobe Gakuin U
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Okamoto T
Kinki Univ. Nara Jpn
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SAWABE Akiyoshi
Laboratory of Environmental Biology and Chemistry, Faculty of Agriculture, Kinki University
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Okamoto Tadashi
Department Of Agricultural Chemistry Faculty Of Agriculture Kinki University
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Ouchi Seiji
Department of Agronomy, Faculty of Agriculture, Kinki University
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Ouchi Seiji
Department Of Agronomy Faculty Of Agriculture Kinki University
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Ouchi Seiji
Department Of Agriculture Kinki University
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Obata Takao
Departmentof Agricultural Chemistry Faculty Of Agricuture Kinki University
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SAWABE Akiyoshi
Institute for Comprehensive Agricultural Sciences, Kinki University
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MORITA Masanori
Joint Research Center, Kinki University
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Sawabe Akiyoshi
Institute For Comprehensive Agricultural Sciences Kinki University
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