Structural, Dielectric, and Piezoelectric Properties of Mn-Doped BaTiO<sub>3</sub>--Bi(Mg<sub>1/2</sub>Ti<sub>1/2</sub>)O<sub>3</sub>--BiFeO<sub>3</sub> Ceramics
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概要
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Mn-doped ($0.9-x$)BaTiO<sub>3</sub>--0.1Bi(Mg<sub>1/2</sub>Ti<sub>1/2</sub>)O<sub>3</sub>--$x$BiFeO<sub>3</sub> ($x = 0.6$, 0.7, and 0.8) ceramics were studied as candidate lead-free piezoelectric materials. The crystal structures were a pseudo-cubic perovskite at $x = 0.6$, a rhombohedral perovskite at $x = 0.8$, and a mixture of the pseudo-cubic and rhombohedral perovskite at $x = 0.7$. The Curie temperature was found to be 470 °C at $x = 0.6$ and more than 600 °C at $x = 0.7$ and 0.8. A strong pinning of domain walls was observed for high-field responses at $x = 0.7$ and 0.8, which was relaxed by high-temperature annealing and subsequent quenching. Piezoelectric properties increased with decreasing $x$, and the small-field piezoelectric constants $d_{33}$ and $d_{31}$ were 94 and 31 pC/N at $x = 0.6$, respectively.
- 2011-09-25
著者
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Watanabe Takayuki
Corporate R&D Headquarters, CANON INC.
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Hayashi Jumpei
Corporate R&D Headquarters, CANON INC.
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Wada Satoshi
Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi
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Kumada Nobuhiro
Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi
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Nakashima Kouichi
Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, Kofu 400-8510, Japan
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FUJII Ichiro
Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi
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Kubota Makoto
Corporate R&D Headquarters, Canon Inc., 3-30-2 Shimomaruko, Ohta, Tokyo 146-8501, Japan
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Yabuta Hisato
Corporate R&D Headquarters, CANON Inc., Ota, Tokyo 146-8501, Japan
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Shimada Mikio
Corporate R&D Headquarters, CANON Inc., Ota, Tokyo 146-8501, Japan
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Mitsui Ryuta
Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi, Kofu 400-8510, Japan
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Fukui Tetsuro
Corporate R&D Headquarters, CANON Inc., Ota, Tokyo 146-8501, Japan
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WATANABE Takayuki
Corporate R&D Headquarters, CANON INC.
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NAKASHIMA Kouichi
Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi
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Fukui Tetsuro
Corporate R&D Headquarters, CANON Inc., Ota, Tokyo 146-8501, Japan
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Wada Satoshi
Interdisciplinary Graduate School of Material Science and Technology, University of Yamanashi, 4-3-11 Takeda, Kofu 400-8511, Japan
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Hayashi Jumpei
Corporate R&D Headquarters, Canon Inc., Ota, Tokyo 146-8501, Japan
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HAYASHI Jumpei
Corporate R&D Headquarters, CANON INC.
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