Sequential Phase Transitions in Sm Substituted BiFeO<sub>3</sub>
スポンサーリンク
概要
- 論文の詳細を見る
The compositional and thermal evolution of the crystal structure of the solid solution Bi<sub>1-x</sub>Sm<sub>x</sub>FeO<sub>3</sub> synthesized at a high pressure of 4 GPa was investigated. It was found that Bi<sub>1-x</sub>Sm<sub>x</sub>FeO<sub>3</sub> with $x = 0.10$ and 0.15 had an antipolar PbZrO<sub>3</sub>-type structure with a $\sqrt{2}a\times 2\sqrt{2}a\times 4a$ perovskite superstructure at room temperature, while that with $x = 0.05$ had the same structure as the parent BiFeO<sub>3</sub> ($x = 0$). The $x = 0.10$ sample transforms from an antipolar PbZrO<sub>3</sub>-type orthorhombic structure to a polar BiFeO<sub>3</sub>-type rhombohedral structure and eventually to a nonpolar GdFeO<sub>3</sub>-type structure on heating as Zr-rich PZT.
- 2011-09-25
著者
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Shimakawa Yuichi
Institute For Chemical Research Kyoto University
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Oka Kengo
Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama 226-8503, Japan
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Kubota Makoto
Corporate R&D Headquarters, Canon Inc., Ota, Tokyo 146-8501, Japan
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Nakamura Yoshitaka
Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan
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Yabuta Hisato
Corporate R&D Headquarters, Canon Inc., Ota, Tokyo 146-8501, Japan
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Miura Kaoru
Corporate R&D Headquarters, Canon Inc., Ota, Tokyo 146-8501, Japan
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Azuma Masaki
Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama 226-8503, Japan
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Kubota Makoto
Corporate R&D Headquarters, Canon Inc., 3-30-2 Shimomaruko, Ohta, Tokyo 146-8501, Japan
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Yabuta Hisato
Corporate R&D Headquarters, CANON Inc., Ota, Tokyo 146-8501, Japan
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Miura Kaoru
Corporate R&D Headquarters, Canon Inc., 3-30-2 Shimomaruko, Ohta, Tokyo 146-8501, Japan
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Nakamura Yoshitaka
Institute for Chemical Research, Kyoto University Gokasho, Uji, Kyoto 611-0011, Japan
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