Synthesis of the Higher-Order Diamondoid Hexamantane Using Low-Temperature Plasmas Generated in Supercritical Xenon
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概要
- 論文の詳細を見る
Diamondoid molecules were synthesized from adamantane (C10H16) using low-temperature plasmas generated in supercritical xenon. The carbon content of the synthesized materials was verified by energy dispersive X-ray spectroscopy, while micro-Raman spectroscopy measurements confirmed that the synthesized materials contained sp3 bonds, the features in the Raman spectra being similar to those found in the Raman spectra of higher order diamondoids. Mass peaks at $m/z = 396$ were most abundant and might be attributed to C30H36 isomers of hexamantane. The synthesis of this particular type of diamondoid is explained by the fewer necessary cleavages of C–C bonds or C–H occurring to form the diamondoid.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2010-07-25
著者
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Terashima Kazuo
Department Of Advanced Materials Science Graduate School Of Frontier Science The University Of Tokyo
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Stauss Sven
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Shizuno Tomoki
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Miyazoe Hiroyuki
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Sasaki Takehiko
Department Of Biomolecular Medicine Akita Graduate University School Of Medicine
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Terashima Kazuo
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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Saito Koya
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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Stauss Sven
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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Shizuno Tomoki
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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Miyazoe Hiroyuki
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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Sasaki Takehiko
Department of Complexity Science and Engineering, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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