Growth and Characterization of Epitaxial InN Films on Sapphire Substrate using an ArF Excimer Laser-Assisted Metalorganic Vapor-Phase Epitaxy (LA-MOVPE)
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概要
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Epitaxial InN films have been grown on sapphire substrate by using an ArF excimer laser-assisted metalorganic vapor-phase epitaxy (LA-MOVPE) as a new potential growth technique. An ArF excimer laser photolytically dissociates NH3 with independent of the growth temperature while photolytical dissociation of trimethylindium (TMI) is not observed. The photolytically dissociated NH3 reacts with TMI to deposit InN film and even single crystalline film is grown. This enables InN film deposition over a wide range of growth temperature, from a room temperature to a very high temperature (700°C). Single crystalline InN films with smooth surfaces are successfully grown in the temperature range of 350-700°C with a variety of condition. The characterization of the InN films grown over a wide range of temperature and condition enables to find out some important evidences about the InN properties, especially the band gap energy. Interestingly, this new growth technique provides a growth rate of more than 0.5 μm/h just by flowing a very little amount (${\sim}100$ sccm) of NH3. While to obtain such growth rate in our conventional MOVPE a total amount of ${\sim}6000$ sccm NH3 gas is required. The electrical properties are still found to be poor compared to the recently reported good results. Important evidences as to what species is responsible for poor electrical properties in the grown InN are discussed.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2003-12-15
著者
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BHUIYAN Ashraful
Department of Electrical & Electronics Engineering, Fukui University
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HASHIMOTO Akihiro
Department of Electrical & Electronics Engineering, Fukui University
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Yamamoto Akio
Department Of Applied Chemistry Graduate School Of Science And Engineering And Advanced Research Cen
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Tanaka Tatsuya
Department of Electrical & Electronics Engineering, Fukui University, 3-9-1 Bunkyo, Fukui 910-8507, Japan
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Bhuiyan Ashraful
Department of Electrical & Electronics Engineering, Fukui University, 3-9-1 Bunkyo, Fukui 910-8507, Japan
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Kasashima Ken
Department of Electrical & Electronics Engineering, Fukui University, 3-9-1 Bunkyo, Fukui 910-8507, Japan
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Kasashima Ken
Department of Electrical & Electronics Engineering, Fukui University, 3-9-1 Bunkyo, Fukui 910-8507, Japan
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