Vacuum UV Photoabsorption Spectra of Silane and Disilane: Molecular Orbital Calculation of Electronic States

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概要

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• Ab initio molecular orbital calculations have been performed for the assignment of vacuum ultraviolet photoabsorption spectra of SiH4 and Si2H6. Strong peaks in the absorption spectra are primarily due to Rydberg transitions of the Si–H and Si–Si bonding electrons to the 4$s$, 4$p$, and 4$d$ orbitals. Substantial contributions of the valence excitations are revealed.

• 1989-02-20

著者

• Kawasaki Masahiro

  Chemistry Department Of Resources Faculty Of Engineering Mi'e University

• Sato Hiroyasu

  Chemistry Department Of Resources Faculty Of Engineering Mi'e University

• KAWAI Eikichi

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University

• Kawai Eikichi

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University, Tsu 514

• Kasatani Kazuo

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University, Tsu 514

• Hirao Kimihiko

  Faculty of General Education, Nagoya University, Chigusa, Nagoya 464

• Kasatani Kazuo

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University

• Sato Hiroyasu

  Chemical Institute, College of Liberal Arts, Kagoshima University

• Sato Hiroyasu

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University, Tsu 514

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