Tris(2,2'-bipyridine)ruthenium(II) in sodium dodecyl sulfate-.GAMMA.-alumina hemimicelles. Enhanced electron transfer and exchange hemimicellization with 1,1'-dimethyl-4,4'-bipyridinium.

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概要

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• On addition of 1,1′-dimethyl-4,4′-bipyridinium (methyl viologen, MV<SUP>2+</SUP>) to tris(2,2′-bipyridine)ruthenium(II) (R<SUP>2+</SUP>) solubilized in sodium dodecyl sulfate (SDS)-γ-alumina hemimicelles (HM), an effective quenching due to electron transfer occurs in HM. Addition of a large amount of MV<SUP>2+</SUP> expels R<SUP>2+</SUP> out of HM into the aqueous phase, as a result of exchange hemimicellization.

• 公益社団法人 日本化学会の論文

著者

• Kasatani Kazuo

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University

• SATO Hiroyasu

  Chemistry Department of Resources, Faculty of Engineering, Mi'e University

• Sato Hiroyasu

  Chemical Institute, College of Liberal Arts, Kagoshima University

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