Highly aggregated state of the dye with the detergent in the premicellar region as revealed by resonance raman spectra.
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概要
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Resonance Raman spectra of 3,3′-diethylthiacarbocyanine iodide–sodium dodecyl sulfate (SDS) system are characterized by [SDS]-dependent change of band intensities. The change was much larger than that accompanied with the shift of monomer-dimer equilibrium in the aqueous solution. The spectra for [SDS]<<critical micelle concentration (cmc) resemble that of the dye in the solid state, indicating the highly-aggregated state of the dye caused by the interaction with the detergent.
- 公益社団法人 日本化学会の論文
著者
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Kawasaki Masahiro
Chemistry Department Of Resources Faculty Of Engineering Mi'e University
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Katsumata Masaaki
Chemistry Department of Resources, Faculty of Engineering, Mie University
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Kasatani Kazuo
Chemistry Department of Resources, Faculty of Engineering, Mi'e University
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Kasatani Kazuo
Chemistry Department of Resources, Faculty of Engineering, Mie University
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Sato Hiroyasu
Chemical Institute, College of Liberal Arts, Kagoshima University
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