Two-photon excitation spectra of 1-azabicyclo(2.2.2)octane and trimethylamine.
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概要
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The two-photon fluorescence excitation spectra of 1-azabicyclo[2.2.2]octane (ABCO) and trimethylamine were measured in the excitation wavelength range of 410–520 nm. The effect of the polarization (linear or circular) indicates that the symmetries of the upper states are \tildeA<SUP>1</SUP>A<SUB>1</SUB>, \tildeB<SUP>1</SUP>A<SUB>1</SUB>, and \tildeC<SUP>1</SUP>E for ABCO while \tildeA<SUP>1</SUP>A<SUB>1</SUB> and \tildeB<SUP>1</SUP>E for trimethylamine in C<SUB>3v</SUB> point group approximation. Rotational envelopes for the sequence structures are calculated forcircularly and linearly polarized light excitation and are in good agreement with experiment.
- 公益社団法人 日本化学会の論文
著者
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Kawasaki Masahiro
Chemistry Department Of Resources Faculty Of Engineering Mi'e University
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Sato Hiroyasu
Chemistry Department Of Resources Faculty Of Engineering Mi'e University
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Kasatani Kazuo
Chemistry Department of Resources, Faculty of Engineering, Mi'e University, Tsu 514
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Kuno Hitoshi
Chemistry Department of Resources, Faculty of Engineering, Mi'e University
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Kuno Hitoshi
Chemistry Department of Resources, Faculty of Engineering, Mi'e University
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Kasatani Kazuo
Chemistry Department of Resources, Faculty of Engineering, Mi'e University
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Sato Hiroyasu
Chemical Institute, College of Liberal Arts, Kagoshima University
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