Ion-Molecule Reactions in Acetaldehyde and Methanol
スポンサーリンク
概要
- 論文の詳細を見る
The thermal energy ion-molecule reactions in acetaldehyde and methanol have been studied by mass spectrometry using a pulsed ion source. The rate constants of transfer of light hydrogen and deuterium from methyl and formyl groups of acetaldehyde have been separately treated, and those of transfer of light hyd rogen from methyl and formyl groups have been estimated to be 0.98 × 10<SUP>-9</SUP> and 1.97 × 10<SUP>-9</SUP>cm<SUP>3</SUP> · molecule<SUP>-1</SUP> · sec<SUP>-1</SUP>, respectively. In the methanol system, the indirect isotope effect and the ion repeller voltage dependence on the rate constants for hydrogen transfer reactions are given and compared with the results reported by other workers.
- 日本質量分析学会の論文
著者
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Matsumoto Akira
Department Of Aeronautics And Astronautics Faculty Of Engineering Kyushu University
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DOHMARU TAKAAKI
Radiation Center of Osaka Prefecture
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HAYAKAWA TERUO
Department of Applied Chemistry and Dapartment of Chemistry, University of Osaka Prefecture
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OKADA SATOSHI
Radiation Center of Osaka Prefecture
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TANIGUCHI SETSUO
Radiation Center of Osaka Prefecture
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