Further Discussion of Correlation between Brittleness and Network Structure of Triallyl Isocyanurate Resins
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概要
- 論文の詳細を見る
Attempts to improve the toughness of triallyl isocyanurate (TAIC) resins were unsuccessful using the procedures developed for diallyl phthalate (DAP) resins as typical allyl resins by considering microinhomogenization of the DAP resin during polymerization beyond the gel-point conversion. This demonstrates the difference in network structure of TAIC and DAP resins. The structure of branched TAIC prepolymer was characterized as dendritic by SEC-MALLS-viscometry. Thus, an alternative explanation for the brittleness of TAIC resins is provided: the insufficient growth of the network structure of TAIC resin because of steric hindrance on the crosslinking reaction between sterically crowded growing polymer radical and pendant allyl groups belonging to the rigid primary polymer chain.
- 関西大学の論文
著者
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Aota Hiroyuki
Department Of Applied Chemistry
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Aota Hiroyuki
Department Of Chemistry And Materials Engineering Faculty Of Chemistry Materials And Bioengineering
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TAKAYAMA Yoshihiro
Nippon Kasei Chemical Co., Ltd.
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Takayama Yoshihiro
Nippon Kasei Chemical Co. Ltd.
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Hirao Chikaomi
Department Of Applied Chemistry
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Toridome Hiroyuki
Nippon Kasei Chemical Co. Ltd.
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Matsumoto Akira
Department Of Applied Chemistry
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MATSUDA Tomoya
Department of Applied Chemistry
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Matsumoto Akira
Department Of Aeronautics And Astronautics Faculty Of Engineering Kyushu University
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