The reduction of hexakis(urea)chromium(III) ions at the dropping mercury electrodes.
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概要
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The polarographic reduction of hexakis(urea) chromium (III) ions at the dropping mercury electrode has been studied in various supporting electrolyte solutions. This complex exhibits two irreversible reduction waves; the first corresponds to Cr(III)→Cr(II), and the second, to Cr(II)→Cr(0). The kinetic parameters of the electrode reactions were determined in various supporting electrolyte solutions and at varied ionic strengths by means of Tast polarography. The differential-pulse polarographic characteristics of this complex are also given.
- 公益社団法人 日本化学会の論文
著者
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Yamada Akifumi
Department Of Chemistry Faculty Of Engineering Nagaoka University Of Technology
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Tanaka Nobuyuki
Department Of Botany Kochi Prefectural Makino Botanical Garden
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Yoshikuni Tadatsugu
Department of Chemistry, Faculty of Science, Kanazawa University
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Nakabayashi Yasuo
Department of Chemistry, Faculty of Science, Tohoku University
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