The Synthesis and Properties of <I>trans</I>-[CrCl<SUB>2</SUB>(NH<SUB>3</SUB>)<SUB>4</SUB>]Cl·H<SUB>2</SUB>O

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概要

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• A simple method for the synthesis of <I>trans</I>-dichlorotetraamminechromium(III) chloride monohydrate was developed, and the configuration of the complex obtained was confirmed by measurements of the infrared and visible absorption spectra. It was found that the <I>cis</I>-<I>trans</I> isomerization took place in the solid state upon the thermal treatment of the complex at 200°C. The enthalpy change for the reaction was calculated to be 1.2 kcal·mol<SUP>−1</SUP> by an analysis of the DSC curve.

• 公益社団法人 日本化学会の論文

著者

• Tanaka Nobuyuki

  Department Of Botany Kochi Prefectural Makino Botanical Garden

• Nagase Kenzo

  Department of Chemistry, College of General Education, Tohoku University

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