Preparation of several 1,5,5,11,11-pentamethyltricyclo-(6.2.1.02,6)undecane derivatives.
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概要
- 論文の詳細を見る
1,6-Diketone, available in eight steps from homocamphorquinone, was converted into 1,5,5,11,11-pentamethyltricyclo[6.2.1.0<SUP>2,6</SUP>]undecan-7-one by treatment with potassium <I>t</I>-butoxide and then lithium dimethylcuprate, while α,α-dimethyl-γ-valerolactone, prepared in five steps from homocamphor, was converted into 1,5,5,11,11-pentamethyltricyclo[6.2.1.0<SUP>2,6</SUP>]undec-2-en-4-one by treatment with diphosphorus pentoxide–methanesulfonic acid.
- 公益社団法人 日本化学会の論文
著者
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Inouye Yoshinobu
Department Of Chemistry The University Of Tsukuba
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Kakisawa Hiroshi
Department Of Chemistry University Of Tsukuba
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Fukaya Chikara
Department of Chemistry, The University of Tsukuba
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Kakisawa Hiroshi
Department of Chemistry, The University of Tsukuba
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