Acyliminium cyclization of several chiral N-alkenylsuccinimide derivatives.

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概要

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• The acyliminium intermediate derived from (3<I>R</I>,4<I>R</I>)-<I>N</I>-(3-butenyl)-3,4-bis(benzyloxy)succinimide cyclized to give (8a<I>S</I>)- and (8a<I>R</I>)-hexahydro-3(2<I>H</I>)-indolidinone derivatives. On the other hand, those derived from <I>N</I>-3-hexenyl derivatives afforded (8a<I>S</I>)-hexahydro-3(2<I>H</I>)-indolidinone(s) exclusively. The geometry of the double bond reflected the stereochemistry of the products.

• 公益社団法人 日本化学会の論文

著者

• Inouye Yoshinobu

  Department Of Chemistry The University Of Tsukuba

• Kakisawa Hiroshi

  Department Of Chemistry University Of Tsukuba

• Ohwada Jun

  Department of Chemistry, University of Tsukuba

• Kimura Motoko

  Department of Chemistry, University of Tsukuba

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