Upon DNP-aromatic rule. Effect of chromophore exchange on the CD spectra of N-DNP-arylalkylamines.
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概要
- 論文の詳細を見る
CD spectra of the analogs of aromatic DNP-α-amino acids and the related <I>N</I>-DNP-arylalkylamines, in which the positions of the two chromophoric groups were exchanged with each other, were studied. The analogs, in which the DNP-amino group is separated from the asymmetric carbon, did not show any marked Cotton effect near 400 nm, indicating the importance of direct attachment of the DNP–NH group to the chiral carbon atom for showing the characteristic CD spectra of <I>N</I>-DNP-aromatic α-amino acids.
- 公益社団法人 日本化学会の論文
著者
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Kawai Masao
Mitsubishi-Kasei Institute of Life Sciences
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Nagai Ukon
Mitsubishi-Kasei Institute of Life Sciences
関連論文
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