A method for determining absolute configuration of cycloalkanamines and related compounds by CD spectra of their 2,4-dinitrophenyl derivatives.
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概要
- 論文の詳細を見る
<I>N</I>-(2,4-Dinitrophenyl) derivatives of cycloalkanamines and related compounds having an amino and an aromatic groups in vicinal positions were prepared. Their CD spectra exhibited marked Cotton effect around 400 nm, the sign of which was shown to coincide with the chirality between the two chromophore-bearing bonds. This relation, as a special example of exciton chirality method, is useful for determining absolute configuration of cyclic compounds having a primary amino group.
- 公益社団法人 日本化学会の論文
著者
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Butsugan Yasuo
Department Of Applied Chemistry Nagoya Institute Of Technology
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Nagai Ukon
Mitsubishi-Kasei Institute of Life Sciences
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Kawai Masao
Department of Synthetic Chemistry, Nagoya Institute of Technology
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Kawai Masao
Department of Appliced Chemistry, Nagoya Institute of Technology
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Iwase Teruhiko
Department of Synthetic Chemistry, Nagoya Institute of Technology
関連論文
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- Studies on the Construction of Allosteric Model Peptides Carrying β-Cyclodextrin and Picolylamino or Picolynylamino Group
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- Functional Molecules Based on Bridged Gramicidin S Derivatives
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- Possible interpretation of inactivity of novel gramicidin S analogs by CD spectral analysis of tetrapeptide derivatives related to the analogs.
- A method for determining absolute configuration of cycloalkanamines and related compounds by CD spectra of their 2,4-dinitrophenyl derivatives.