The crystal structure of 11-(p-bromophenyl)-11-cyano-12-phenyl-6b-(1-pyrrolidinyl)-6b,6c,11,12a-tetrahydroindeno(1'2':3,4)-cyclopenta(1,2-a)acenaphthylene acetone solvate.
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概要
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The title compound crystallizes in the triclinic space group P\bar1 with two fomrula units in a unit cell of dimensions; <I>a</I>=11.621(3), <I>b</I>=15.177(3), <I>c</I>=10.229(2) Å, α=95.63(2), β=105.46(2), and γ=76.43(2)°. The crystal structure was solved by a conventional heavy-atom method and refined by block-diagonal least-squares procedures to give a final <I>R</I> value of 0.050 for 3428 reflections, with <I>F</I><SUB>o</SUB>>2σ(<I>F</I><SUB>o</SUB>), collected on a four-circle diffractometer. The bond distance shared between the acenaphthene and the cyclopentane rings is unusually long at 1.596(6) Å, which may result from the additional strain induced by the fusion of these rings. The solvent molecules are disordered in the channel composed of the main molecules.
- 公益社団法人 日本化学会の論文
著者
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Tsuge Otohiko
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences Kyushu University
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Uechi Tetsuo
College of General Education, Kyushu University 01
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Kanemasa Shuji
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences Kyushu University
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Kanemasa Shuji
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University 86
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Okita Shigeru
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University 86
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