A Diels-Alder cycloaddition and electrocyclization sequence as a new (6.5) annelation method to benzene ring.
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概要
- 論文の詳細を見る
The Diels–Alder reactions of 1-aryl-2-methylene-3-buten-1-ols, readily available from chloroprene and aryl ketones, with olefinic dienophiles and subsequent electrocyclic reactions of the cycloadducts offer a new method of [6.5] annelation to benzene ring. By this way, tetrahydrofluorene skeletons bearing functional groups can be prepared. Stereochemical aspect of this sequence is also discussed.
- 公益社団法人 日本化学会の論文
著者
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Tsuge Otohiko
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences Kyushu University
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Wada Eiji
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences Kyushu University
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Wada Eiji
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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Kanemasa Shuji
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Science, Kyushu University
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