Double cycloaddition reaction of imidazolium methylides. Intermolecular 1,3-dipolar and intramolecular Diels-Alder cycloaddition reactions.
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概要
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Such imidazolium methylides as imidazolium dicyanomethylide and bis(ethoxycarbonyl)methlide react with the methylenecyclopropenes with unsaturated substituents at the 4-position in the fashion of double cycloaddition reaction, leading to the novel cage compounds, which involves an intermorecular 1,3-dipolar cycloaddition reaction and an intramolecular Diels-Alder reaction.
- 公益社団法人 日本化学会の論文
著者
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Tsuge Otohiko
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences Kyushu University
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Takenaka Shigeori
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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Kanemasa Shuji
Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Science, Kyushu University
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