Diazomethane ring-expansion of (-)-D3-trishomocubanone. Preparation and chiroptical properties of a series of (m.1.1)triblattanes.
スポンサーリンク
概要
- 論文の詳細を見る
Optically active [3.1.1], [4.1.1], [5.1.1], and [6.1.1]triblattanes were prepared through the diazomethane ring-expansion of (−)-D<SUB>3</SUB>-trishomocubanone. The absolute molecular rotations of [<I>m</I>.1.1]triblattanes were found to increase with <I>m</I> begining from <I>m</I>=0 till <I>m</I>=2. On going from <I>m</I>=2 to <I>m</I>=3, [M]<SUB>D abs.</SUB> abruptly drops, then the value remains almost constant till <I>m</I>=6.
- 公益社団法人 日本化学会の論文
著者
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Naemura Koichiro
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Hashimoto Masaki
Department Of Cardiology Hiroshima Prefectural Hospital
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Nakazaki Masao
Department Of Chemistry Faculty Of Engineering Science Osaka University
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