The Synthesis and Absolute Configuration of Optically Active Tricyclo[4.3.0.0<SUP>3,8</SUP>]nonane (Twist-brendane)
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概要
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(−)-Tricyclo[4.3.0.0<SUP>3,8</SUP>]nonane ("twist-brendane") was synthesized <I>via</I> (−)-tricyclo[4.3.0.0<SUP>3,8</SUP>]nonan-2-one ("twist-brendan-2-one"). The absolute configuration, (1<I>R</I>,3<I>S</I>,6<I>S</I>,8<I>R</I>)-tricyclo[4.3.0.0<SUP>3,8</SUP>]nonane was assigned to (−)-twist-brendane by correlating with (−)-<I>endo</I>-5-carboxybicyclo[2.2.1]heptane.
- 公益社団法人 日本化学会の論文
著者
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Naemura Koichiro
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Nakazaki Masao
Department Of Chemistry Faculty Of Engineering Science Osaka University
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