Synthesis and enantiomer recognition of dipodands and crown ethers containing the 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene residue as the chiral subunit.
スポンサーリンク
概要
- 論文の詳細を見る
Five new optically active crown ethers and six optically active dipodands are reported. The crown ethers were synthesized by using (+)-(1<I>S</I>,4<I>R</I>,5S,8<I>R</I>)-2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-diol and (+)-(1<I>S</I>,4<I>R</I>,5<I>S</I>,8<I>R</I>)-4,8-bis(hydroxymethyl)-2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene as a chiral subunit and the dipodands contained the 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene residue as a chiral anchor group. The enantiomer recognition behaviour of these compounds was evaluated by the enantiomer differential transport of methyl (±)-phenylglycinate and (±)-1,2-diphenylethylamine hydrochloride through bulk liquid membrane.
- 公益社団法人 日本化学会の論文
著者
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Naemura Koichiro
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Komatsu Masanori
Department Of Livestock And Grassland Science National Agricultural Research Center For Western Regi
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Chikamatsu Hiroaki
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Yamanaka Masatoshi
Department of Chemistry, Faculty of Engineering Science, Osaka University
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