Synthesis of chiral crown ethers derived from trans, trans- and cis, trans-2,2'-spirobiindan-1,1'-diols. Their chiral recognition and complexation properties.
スポンサーリンク
概要
- 論文の詳細を見る
<I>trans</I>,<I>trans</I>-2,2′-Spirobiindan-1,1′-diol (<B>1</B>) was resolved as its (−)-ω-camphanic ester and the absolute rotation of the glycol <B>1</B> was determined. Two crown ethers and the acyclic analog were derived from (+)-<B>1</B>. Two crown ethers incorporating (+)-<I>cis</I>,<I>trans</I>-2,2′-spirobiindan-1,1′-diol were also prepared. Their chiral recognition properties in transport of methyl (±)-phenylglycinate hydrochloride and abilities to extract alkali metal picrates were investigated.
- 公益社団法人 日本化学会の論文
著者
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Naemura Koichiro
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Nakazaki Masao
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Nakazaki Masao
Department of Chemistry, Faculty of Engineering Science, Osaka University
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Ebashi Iwao
Department of Chemistry, Faculty of Engineering Science, Osaka University
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