The electrochemical cleavage of carbon-halogen bonds of haloferrocenes.
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概要
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The cyclic voltarmmetric studies for haloferrocenes, FcX (X=Cl, Br, and I), in etylene glycol dimethyl ether at −45 °C have been reported. The cyclic voltammogram and the absorption spectrum of the solution after the exhaustive controlled-potential reduction for the reduction step of haloferrocene show a quantitative formation of ferrocene and a cleavage of the carbon–halogen bond of haloferrocene.
- 公益社団法人 日本化学会の論文
著者
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Saji Tetsuo
Department Of Chemical Engineering Tokyo Institute Of Technology
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Ito Naoyuki
Department of Chemical Engineering, Tokyo Institute of Technology
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