Partition parameters for three redox forms of viologen in a nonionic micellar solution.
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概要
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The partition parameters of 1,1′-dimethyl-4,4′-bipyridinium (<B>1</B>), 1-decyl-1′-methyl-4,4′-bipyridinium (<B>2</B>), and 1-dodecyl-1′-methyl-4,4′-bipyridinium (<B>3</B>) between the micellar and water phases were determined by electrochemical methods. It was shown that <B>1</B><SUP>0</SUP>, <B>2</B><SUP>\underset.+</SUP>, <B>2</B><SUP>0</SUP>, and <B>3</B><SUP>2+</SUP> are almost completely solubilized in the micellar phase and that <B>1</B><SUP>2+</SUP>, <B>1</B><SUP>\underset.+</SUP> and <B>2</B><SUP>2+</SUP> are partitioned into two phases.
- 公益社団法人 日本化学会の論文
著者
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Suga Kosaku
Department Of Biomolecular Engineering Tokyo Institute Of Technology
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Sasaki Hiroaki
Department Of Cardio-vascular Surgery National Cardio-vascular Center
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Saji Tetsuo
Department Of Chemical Engineering Tokyo Institute Of Technology
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Hoshino Katsuyoshi
Department Of Image Science Faculty Of Engineering Chiba University
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Sasaki Hiroaki
Department of Chemical Engineering, Tokyo Institute of Technology
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Hoshino Katsuyoshi
Department of Chemical Engineering, Tokyo Institute of Technology
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