CD spectra of 2,4-dinitrophenyl derivatives of .ALPHA.-amino acids having polynuclear aromatic group in the side chain. Absolute configuration of 3-(9-anthryl)alanine.
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概要
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CD spectra of 2,4-dinitrophenyl (Dnp) derivatives of α-amino acids having polynuclear aromatic group in the side chain with L- and D-configuration showed negative and positive Cotton effect, respectively, around 400 nm in consistent with previously proposed Dnp-aromatic rule. Application of the rule revealed D-configuration of levorotatory 3-(9-anthryl)alanine, which was further confirmed by chiroptical comparison of the 2,4-dinitrophenyl derivative and its <I>p</I>-methoxyanilide.
- 公益社団法人 日本化学会の論文
著者
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Sisido Masahiko
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Kawai Masao
Department Of Applied Chemistry Nagoya Institute Of Technology
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Butsugan Yasuo
Department Of Applied Chemistry Nagoya Institute Of Technology
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Imanishi Yukio
Department Of Material Chemistry Graduate School Of Engineering Kyoto Univeresity
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Matsuura Taketoshi
Department of Applied Chemistry, Nagoya Institute of Technology
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Egusa Syun
Department of Polymer Chemistry, Kyoto University
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Egusa Syun
Department of Polymer Chemistry, Faculty of Engineering, Kyoto University
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Kawai Masao
Department of Appliced Chemistry, Nagoya Institute of Technology
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Sisido Masahiko
Research Center for Medical Polymers and Biomaterials, Kyoto University
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