.ALPHA.,.BETA.-Epoxy sulfoxides as useful intermediates in organic synthesis. I. A novel synthesis of dialkyl ketones and a synthesis of aldehydes from ketones by one carbon elongation.
スポンサーリンク
概要
- 論文の詳細を見る
Treatment of α,β-epoxy sulfoxides, prepared from 1-chloroalkyl phenyl sulfoxides with ketones or aldehydes, with sodium benzeneselenolate gives dialkyl ketones or aldehydes in good yields under mild conditions. The mechanism of this reaction and an application of this process to a formal total synthesis of dihydrojasmone are described.
- 公益社団法人 日本化学会の論文
著者
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Satoh Tsuyoshi
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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Yamakawa Koji
Faculty Of Pharmaceutical Science Science University Of Tokyo
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Kaneko Youhei
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Izawa Takao
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Sakata Kiichi
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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