Electron transfer initiated replacement of bromo and methoxyl groups with aryliminodi-, arylamino-, and arylthiomagnesium reagents.
スポンサーリンク
概要
- 論文の詳細を見る
The replacement of bromo and methoxyl groups of fluorenone, <I>N</I>-(9-fluorenylidene)aniline, and α-benzylideneacetophenone with ArSMgBr(<B>S</B>), ArNHMgBr(<B>NH</B>), and ArN(MgBr)<SUB>2</SUB>(<B>N</B>) were examined. The distribution of products obtained in the reactions with the reagents including ArMgBr(<B>C</B>) and ArOMgBr(<B>O</B>) were explained in terms of relative electron-donating abilities of reagents: <B>C</B>><B>S</B>><B>NH</B>><B>N</B>><B>O</B>.
- 公益社団法人 日本化学会の論文
著者
-
Nakagawa Yasuhiro
Department Of Psyhosomatic Medicine School Of Medicine Toho University
-
Yoshida Masatoshi
Department Of Chem. Eng. Tohoku Univ.
-
Okubo Masao
Department of Chemistry, Faculty of Science and Engineering, Saga University
-
Yoshida Masatoshi
Department of Chemistry, Faculty of Science and Engineering, Saga University
-
Yanase Hidenobu
Department of Chemistry, Faculty of Science and Engineering, Saga University
関連論文
- Fault Detection in Chemical Processes Using Discriminant Analysis and Control Chart
- Concentration Estimation for Decentralized Temperature Control of a Packed-Bed Reactor
- Spectral Uncertainty Modelling from Experimental Data with Application to Robust Modal Control of a Packed-bed Column
- Application of μ-Interaction Measures for Decentralized Temperature Control of Packed-Bed Chemical Reactor
- IMC Based Robust Pole Placement Procedure for Modal Control of One-Dimensional Heat Conduction Process
- Biofeedback Therapy in Chronic Headaches : Prognostic Investigation
- Dynamic Analysis for Stacked Molten Carbonate Fuel Cell by Use of a Rigorous Mathematical Model
- PARAMETER IDENTIFICATION FOR A PARABOLIC DISTRIBUTED PARAMETER SYSTEM USING THE FINITE INTEGRAL TRANSFORM TECHNIQUE
- Effects of coculture with the septum on the expression of long-term potentiation in organotypic hippocampal slice cultures
- Control of Axial Temperature Distribution in a Packed-Bed Reactor
- Azoxy- and azoferrocenes, and N-(ferrocenylarylmethylene)anilines formed via aryliminodimagnesium(IDMg) procedure. Effect of ferrocenyl group on IDMg reaction and molecular structures of products.
- The thermal decomposition of cyanodiphenylmethyl t-butyl peroxide: An example of C-O bond scission.
- Optical Activity and Absolute Configuration of 2,3 :6,7-Dibenzobicyclo [3.3.1]nona-2,6-diene Derivatives
- Aryliminodimagnesium reagents. VII. The moderate electron-donating ability estimated by oxidation peak potentials.
- Aryliminodimagnesium reagents. XI. Two-electron oxidation of the reagent molecules in the reaction with some oxidizing agents and with strongly push-pull substituted .ALPHA.-benzylideneacetophenones.
- Aryliminodimagnesium reagents. XIV. Reactions with nitrobenzenes having electronegative ortho-substituents. Effects of reaction conditions on condensation, replacement, and substitution.
- Aryliminodimagnesium reagents. XV. Condensation with nitrobenzene. Formation of unsymmetrical azobenzens favored by long-chain p-alkoxy-substituted reagents.
- Substituent effects on 15N and 17O NMR chemical shifts in 4'-substituted trans-NNO-azoxybenzenes.
- Aryliminodimagnesium reagents. III. The deoxygenative condensation with nitroso- and nitroarenes: Electronic effect of substituents on product distribution.
- Aryliminodimagnesium reagents. V. The reaction with bifunctional nitroarenes.
- Electron transfer initiated replacement of bromo and methoxyl groups with aryliminodi-, arylamino-, and arylthiomagnesium reagents.
- Ketyl Radicals Formed in Grignard Reaction. III. Steric Effects on the Formation of Radicals
- Evidence for electron-transfer process in abnormal Grignard reactions. Enolization and .ALPHA.-diketone formation.
- Grignard reaction of peroxides containing neighboringnitrogen atom.
- Iminodimagnesium reagents. Condensation reaction with ketones. Direct preparation of anils and a hydrazone of xanthone.
- The Reaction of α-Ethoxybenzyl t-Butyl Peroxide with Grignard Reagents
- Abnormal Grignard Reaction of 2,4,6-Trimethylbenzophenone: An Electron-transfer Mechanism