The thermal decomposition of cyanodiphenylmethyl t-butyl peroxide: An example of C-O bond scission.
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概要
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The thermal decomposition of cyanodiphenylmethyl <I>t</I>-butyl peroxide was investigated. The peroxide is abnormally stable and decomposes slowly at 130–135 °C, and the main reaction product is tetraphenylsuccinonitrile. A main reaction path including the C–O bond scission, in contrast to the case of triphenylmethyl <I>t</I>-butyl peroxide, is proposed.
- 公益社団法人 日本化学会の論文
著者
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Okubo Masao
Department of Chemistry, Faculty of Science and Engineering, Saga University
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Iba-Imai Emiko
Department of Chemistry, Faculty of Science and Engineering, Saga University
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Mizuta Hiroko
Department of Chemistry, Faculty of Science and Engineering, Saga University
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Kawamoto Takumi
Department of Chemistry, Faculty of Science and Engineering, Saga University
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