Evidence for electron-transfer process in abnormal Grignard reactions. Enolization and .ALPHA.-diketone formation.
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概要
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The effect of 2,6-dimethyl groups on enolization <I>vs.</I> addition in the reaction of PhMgBr with PhCH<SUB>2</SUB>COPh, and also the formation of α-diketone from 2,4,6-Me<SUB>3</SUB>C<SUB>6</SUB>H<SUB>2</SUB>COCl by the treatment with MeMgX and <I>i</I>-PrMgX in the presence of CoCl<SUB>2</SUB>, were studied. The results were discussed on the basis of electron-transfer mechanism.
- 公益社団法人 日本化学会の論文
著者
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Morigami Yoshiaki
Department of Chemistry, Faculty of Science and Engineering, Saga University
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Okubo Masao
Department of Chemistry, Faculty of Science and Engineering, Saga University
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Suenaga Reiko
Department of Chemistry, Faculty of Science and Engineering, Saga University
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