Synthesis of opically active 3-morpholinecarboxylic acid and tetrahydro-2H-1,4-thiazine-3-carboxylic acid.
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概要
- 論文の詳細を見る
A convenient synthesis of optically active 3-morpholinecarboxylic acid and its thio analogue, tetrahydro-2<I>H</I>-1,4-thiazine-3-carboxylic acid, has been developed. These intermediates were obtained by reaction of benzyl (<I>S</I>)-<I>N</I>-benzyloxycarbonyl-2-aziridinecarboxylate and its enantiomer with 2-chloroethanol or 2-chloroethanethiol, respectively.
- 公益社団法人 日本化学会の論文
著者
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Okawa Kenji
Department of Chemistry, Faculty of Science, Kwansei Gakuin University
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Kogami Yuji
Department of Chemistry, Faculty of Science, Kwansei Gakuin University
関連論文
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- Studies on 2-aziridinecarboxylic acid. V. Formation of dehydroamino acid containing peptides via the isomerization by NaI of 2-aziridinecarboxylic acid containing peptides.
- Studies on Hydroxy Amino Acids. IV. Syntheses of Several Peptides Containing Aziridinecarboxylic Acid Derived from the Corresponding Hydroxy Amino Acid Derivatives
- Synthesis of threo-3-methylcysteine from threonine.
- Synthesis of opically active 3-morpholinecarboxylic acid and tetrahydro-2H-1,4-thiazine-3-carboxylic acid.