A light-scattering study of temperature effect on micelle formation of N-alkanoyl-N-methylglucamines in aqueous solution.
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概要
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The physicochemical properties of <I>N</I>-alkanoyl-<I>N</I>-methylglucamine in aqueous solution have been studied by applying a Debye plot and small-system thermodynamics to an analysis of static light scattering data in the temperature range from 25 to 55 °C. A small minimum was found in a plot of the critical micelle concentration vs. temperature, instead of the monotonously decreasing tendency, as in the case of poly(oxyethylene) alkyl ether. The temperature dependence of the aggregation number of the micelle and the spread of the aggregation number distribution of micelle are both very small. The standard enthalpy change associated with micelle formation varies from positive to negative as the temperature is raised. The micellization of <I>N</I>-alkanoyl-<I>N</I>-methylglucamine surfactants is discussed separately in terms of the respective contributions from the hydrophilic and hydrophobic groups.
- 公益社団法人 日本化学会の論文
著者
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Sugihara Gohsuke
Department Of Chem.istry Faculty Of Science Fukuoka University
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Murata Yoshio
Department Of Agrobiology Faculty Of Agriculture University Of Tokyo
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Tanaka Mitsuru
Department Of Cardiology Miyazaki Medical Association Hospital
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Okawauchi Makoto
Department of Chemistry, Faculty of Science, Fukuoka University
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Hagio Mayumi
Department of Chemistry, Faculty of Science, Fukuoka University
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Ikawa Yoshitomi
San-Ei Chemical Industries, Ltd.
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IKAWA Yoshitomi
San-Ei Chemical Industries Ltd.
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Tanaka Mitsuru
Department of Applied Chemistry, Faculty of Engineering, Tokushima University
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