A Review of Recent Studies on Aqueous Binary Mixed Surfactant Systems

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概要

• 論文の詳細を見る

• Recent studies on mixed surfactant systems were systematically overviewed, paying special attention to synergism observed in micellization as well as adsorbed film formation upon mixing of a few nonionic surfactants with a variety of surfactants (such as anionics including bile salts and a hybrid type surfactant, cationics including a Gemini type surfactant, different types of nonionics and a zwitterionic surfactant used as a membrane solubilizer) in addition to various combinations of anionics. Through the text, it was shown for each given binary mixed system composed of surfactants 1 and 2 how to estimate not only the composition of mixed micelles (Y2) equilibrated with singly dispersed surfactant species in bulk solution phase, where the mole fraction of 2 in the surfactant mixture is denoted as X2, but also the composition of adsorbed film phase (Z2). Almost all combinations were discussed in terms of the respective interaction parameters, ωR and ωA, in mixed micelles (3-D phase) and in mixed adsorbed film (2-D phase), respectively, surface excess concentration (Γ), partial molecular area (PMA), minimum surface Gibbs energy (G(S)min), and such defined measures as pC20, CMC/C20 etc. for evaluation of synergism.

• 日本油化学会の論文

著者

• Sugihara Gohsuke

  Department of Chemistry, Faculty of Science, Fukuoka University

• Nagadome Shigemi

  Department Of Chemistry Faculty Of Science Fukuoka University

• Sugihara Gohsuke

  Department Of Chem.istry Faculty Of Science Fukuoka University

• Oh Se-Woung

  Department of Chemistry, Mokpo National University

• Ko Jeong-Soo

  Department of Chemistry, Mokpo National University

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