Diastereoselective hydrogenation of methyl 2-[.ALPHA.-(methoxycarbonylamino)-benzyl]acrylate catalyzed by Ru(II) or Rh(I) complexes.
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概要
- 論文の詳細を見る
The title compound was prepared and hydrogenated by using a Ru(II)- or Rh(I)-phosphine catalyst precursor with excellent <I>anti</I>-selectivity, the results indicating that a ligating group, NHCO<SUB>2</SUB>Me, may direct the addition of hydrogen to an olefinic diastereoface proximate to this group which binds the catalyst.
- 公益社団法人 日本化学会の論文
著者
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TSUJI Jiro
Department of Chemical Technology, Kurashiki University of Science and the Arts
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Yamamoto Keiji
Department Of Applied Physics Faculty Of Engineering Tokyo University
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Takagi Masatoshi
Department of Chemical Engineering, Tokyo Institute of Technology
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