Efficient regioselective aldol condensation of methyl ketones promoted by organoaluminium compounds, and its application to muscone synthesis.
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概要
- 論文の詳細を見る
Dialkylaluminium aryloxide in combination with a tertiary amine was found to be a good reagent for regioselective aldol condensation of methyl ketones at the methyl side. Regioselective aldol condensation of 2-octanone was carried out using diisobutylaluminium phenoxide–pyridine. The intramolecular aldol condensation of 2,15-hexadecanedione promoted by the same reagent gave a mixture of dehydromuscones in 65% yield. Its hydrogenation produced muscone.
- 公益社団法人 日本化学会の論文
著者
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Mandai Tadakatsu
Department Of Life Science Kurashiki University Of Science & The Arts
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TSUJI Jiro
Department of Chemical Technology, Kurashiki University of Science and the Arts
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Yamada Toshiro
Department of Chemical Engineering, Tokyo Institute of Technology
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YAMADA TOSHIRO
Department of Chemical Engineering, Kanazawa University
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Kaito Mitsumasa
Department of Chemical Engineering, Tokyo Institute of Technology
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Mandai Tadakatsu
Department of Chemical Engineering, Tokyo Institute of Technology
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