Preparation of matsutake alcohol (1-octen-3-ol) from a butadiene telomer.

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概要

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• A simple preparation of 1-octen-3-ol so called Matsutake alcohol using a butadiene telomer is described: selective hydrogenation of the terminal double bond of 2,7-octadienyl acetate gave 2-octenyl acetate which was converted <I>via</I> palladium-catalyzed allylic rearrangement and hydrolysis into 1-octen-3-ol.

• 公益社団法人 日本化学会の論文

著者

• TSUJI Jiro

  Department of Chemical Technology, Kurashiki University of Science and the Arts

• Yamamoto Keiji

  Department Of Applied Physics Faculty Of Engineering Tokyo University

• Yamamoto Keiji

  Department of Chemistry, Engineering, Tokyo Institute of Technology

• Tsuruoka Katsuhiko

  Department of Chemistry, Engineering, Tokyo Institute of Technology

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