Modification of (S)-N,N-dimethyl-1-[(R)-1',2-bis(diphenylphosphino)-ferrocenyl]ethylamine (BPPFA) as a ligand for asymmetric hydrogenation of olefins catalyzed by a chiral rhodium(I) complex.
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概要
- 論文の詳細を見る
Asymmetric homogeneous hydrogenation of prochiral olefins catalyzed by chiral rhodium(I) complexes was carried out by using several ferrocenylphosphines as ligands which play a key role of the chiral recognition. Modifications of BPPFA were made in order to examine a steric effect of the given substutient at the asymmetric center on the efficiency of the chiral ligands, indicating the parent BPPFA to be superior to the others examined for the asymmetric hydrogenation of highly functionalized olefins.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Keiji
Department Of Applied Physics Faculty Of Engineering Tokyo University
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YAMAMOTO Keiji
Department of Chemical Engineering, Tokyo Institute of Technology
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Wakatsuki Junya
Department of Chemical Engineering, Tokyo Institute of Technology
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Sugimoto Ryuichi
Department of Chemical Engineering, Tokyo Institute of Technology
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