An 27Al NMR study on the complexes present in the solutions of potassium hexathiocyanatoaluminate(III).
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概要
- 論文の詳細を見る
The species present in the solutions of potassium hexathiocyanatoaluminate(III) in various solvents were identified by <SUP>27</SUP>Al NMR spectra of the solutions. In dimethyl sulfoxide solution containing excess KSCN, the spectrum consists of 7 resonances due to [Al(NCS)<I><SUB>n</SUB></I>(DMSO)<SUB>6−<I>n</I></SUB>]<SUP>(3−<I>n</I>)+</SUP> (<I>n</I>=0–6), whereas a single resonance arising from [Al(NCS)<SUB>6</SUB>]<SUP>3−</SUP> was observed in propylene carbonate or acetone.
- 公益社団法人 日本化学会の論文
著者
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Komatsu Noriyuki
Department Of Cell Biology Research Laboratoly School Of Medicine Tokai University
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Yokoi Masatoki
Department of Chemistry, Faculty of Science, Shinshu University
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Kubota Eiji
Department of Chemistry, Faculty of Science, Shinshu University
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Komatsu Noriyuki
Department of Chemistry, Faculty of Science, Shinshu University
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