Sedimentation Potential Measurements and Partial Molar Volumes of Univalent Ions in Water-Acetone Mixtures.
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概要
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Sedimentation potentials and electrical conductivities were measured for NaCl, NaBr, sodium tetraphenylborate Na[BPh<SUB>4</SUB>], and tetraphenylphosphonium chloride [Ph<SUB>4</SUB>P]Cl in water–acetone systems (up to 50 wt% of acetone). Using the data obtained and the reported values of partial molar volumes <I>V</I><SUB>2</SUB><SUP>∞</SUP>, the ionic division of <I>V</I><SUB>2</SUB><SUP>∞</SUP> was carried out. The values of <I>V</I><SUB>2</SUB><SUP>∞</SUP> (Na<SUP>+</SUP>) evaluated for NaCl, NaBr, and Na[BPh<SUB>4</SUB>] were self-consistent and they work as references for ionic division of <I>V</I><SUB>2</SUB><SUP>∞</SUP> (MX).
- 公益社団法人 日本化学会の論文
著者
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Nomura Hiroyasu
Department Of Chemical Engineering Faculty Of Engineering Nagoya University
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NOMURA Hiroyasu
Department of Chemical Engineering, School of Engineering, Nagoya University
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Kawaizumi Fumio
Institute for Molecular Science
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Kubota Eiji
Department of Chemistry, Faculty of Science, Shinshu University
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Hirakawa Hiromitsu
Department of Electrical Engineering, Faculty of Engineering, Kagoshima University
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