A peculiar conformation of normal-chain dicarboxylic acid salts in aqueous solutions.
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概要
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The Raman spectra of adipic acid, pimelic acid, and their salts were observed for various states. The spectra of the acids in aqueous sodium hydroxide solutions were found to be very different from those of the acids in organic solvents. The difference was interpreted, on the basis of normal vibration calculations, as being due to the helix formation of molecules in the former solutions. This tendency toward helical coiling is consistent with the same tendency found for the salts of azelaic acid and suberic acid in our previous study.
- 公益社団法人 日本化学会の論文
著者
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Adachi Koichi
Department Of Cardiovascular Surgery Saitama Medical Center Jichi Medical University
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Fukushima Kunio
Department Of Chemistry Faculty Of Science
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Watanabe Kiyohisa
Department of Chemistry, Faculty of Science, Shizuoka University
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