Synthesis and characterization of a 3-thio-2,4-pentanedionate Pt(II) complex; Bis[dimethylphenylphosphine)[2,4-pentanedione-3-thiolato(2-)-O,S]-platinum(II) prepared by S-S bond cleavage of 2,3-dithio-1,1,4,4-tetraacetylbutane.

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概要

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• 3-Thio-2,4-pentanedionate (tac) complex of platinum(II), [Pt(tac)(PMe<SUB>2</SUB>Ph)<SUB>2</SUB>], has been prepared by treating [PtCl(PMe<SUB>2</SUB>Ph)<SUB>3</SUB>][PF<SUB>6</SUB>] with 2,3-dithio-1,1,4,4-tetraacetylbutane in a KOH/methanol–acetone mixed solution. This complex has been characterized by IR, <SUP>1</SUP>H, <SUP>13</SUP>C, and <SUP>31</SUP>P NMR, secondary ion mass and ESR spectroscopy and cyclic voltammetry.

• 公益社団法人 日本化学会の論文

著者

• Ueno Tamio

  Department Of Agricultural Chemistry Kyoto University

• Ama Tomoharu

  Department Of Chemistry Faculty Of Science Kochi University

• Yamazaki Shinsaku

  Chemistry Laboratory

• Hojo Masashi

  Department Of Chemistry Faculty Of Science Kochi University

• Ueno Tamio

  Department of Agriculture, Kyoto University

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