Metal complexes of amino acids. X. The preparation and characterization of cobalt(III) complexes of the type [Co(N)2(O)4] containing .BETA.-alanine.
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概要
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Three geometrical isomers of the bis(β-alaninato)(oxalato)cobaltate(III) and of the (β-alaninato)(glycinato)(oxalato)cobaltate(III) complexes have been prepared and resolved into their optical isomers. Their structures were assigned on the basis of the electronic absorption, <SUP>1</SUP>H NMR and <SUP>13</SUP>C NMR spectra. The circular dichroism spectra of these complexes have been measured and compared with those of the bis(glycinato)(oxalato)cobaltate(III) complexes.
- 公益社団法人 日本化学会の論文
著者
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Yasui Takaji
Department Of Chemistry Faculty Of Science Kochi University
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Ama Tomoharu
Department Of Chemistry Faculty Of Science Kochi University
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HIGA Matsutake
Department of Chemistry, College of Science, University of the Ryukyus
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Koine Norio
Department Of Applied Chemistry Faculty Of Engineering Ehime University
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Higa Matsutake
Department of Industrial Chemistry, Faculty of Engineering, Ehime University
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