Inversion at the sulfur atom in bis(diethyl sulfide)(1,1,2,2-tetraacetylethane-C,O')platinum(II).
スポンサーリンク
概要
- 論文の詳細を見る
Variable temperature <SUP>1</SUP>H NMR suggests that the metal–carbon bonded Pt(II) complex of 1,1,2,2-tetraacetylethane(dahd=3,4-diacetyl-2,4-hexadiene-2,5-diol), [Pt(dahd-<I>C</I><SUP>3</SUP>,<I>O</I>′)(SEt<SUB>2</SUB>)<SUB>2</SUB>] undergoes two distinct rearrangements at the sulfides, one of which is accompanied by an anomalous dissociation process. From a comparison of the estimated kinetic parameters for inversion, an arrangement of the two sulfides in planar geometry is proposed.
- 公益社団法人 日本化学会の論文
著者
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Ama Tomoharu
Department Of Chemistry Faculty Of Science Kochi University
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Yamazaki Shinsaku
Chemistry Laboratory
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