Interaction between disodium 1,14-tetradecanediyl disulfate and sodium dodecyl sulfate or poly(oxyethylene) nony phenyl ether on alumina.
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概要
- 論文の詳細を見る
The interactions between disodium 1,14-tetradecanediyl disulfate (α,ωC<SUB>14</SUB>) and sodium dodecyl sulfate (SDS) or poly(oxyethylene) nonyl phenyl ether (NP 7.5) on α-alumina have been studied by measuring the zeta potential, the mean particle size, the amounts of surfactants adsorbed, and the fluorescence spectra of pyrene. When α,ωC<SUB>14</SUB>, SDS, or NP 7.5 as a second additive is added to alumina previously flocculated by the addition of SDS or α,ωC<SUB>14</SUB>, as a first additive, the flocculated alumina redisperses in the α,ωC<SUB>14</SUB>–SDS and α,ωC<SUB>14</SUB>–NP 7.5 systems. For the α,ωC<SUB>14</SUB>–SDS and α,ωC<SUB>14</SUB>–NP 7.5 systems, the redispersion of alumina proceeds in such a manner that the hydrophobic parts of SDS or NP 7.5 are in contact with the α,ωC<SUB>14</SUB>-coated alumina and the hydrophilic polar groups direct out to aqueous solution, resulting in the formation of mixed bilayers on the alumina, while for the α,ωC<SUB>14</SUB>–SDS system the adsorption of SDS on the α,ωC<SUB>14</SUB>-coated alumina is not enough to attain the redispersion of alumina. The measurement of the ratio <I>I</I><SUB>1</SUB>⁄<I>I</I><SUB>3</SUB> of intensities of the first and third vibrionic bands of the pyrene monomer fluorescence spectra indicates that pyrene is solubilized in a much lower polar site for the α,ωC<SUB>14</SUB>–SDS mixed bilayer than for the mixed bilayer of α,ωC<SUB>14</SUB>–NP 7.5.
- 公益社団法人 日本化学会の論文
著者
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Esumi Kunio
Department Of Applied Chemistry And Institute Of Colloid And Interface Science Science University Of
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Meguro Kenjiro
Department of Applied Chemistry and Institute of Colloid and Interface Science, Science University of Tokyo
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Sakamoto Yuichi
Department of Applied Chemistry and Institute of Colloid and Interface Science, Science University of Tokyo
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Asano Yuki
Department of Applied Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo
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