Surface Activities of Mixtures of Partially-Quaternized 2-Vinylpyridine Telomers and Cationic Gemini Surfactant

スポンサーリンク

概要

• 論文の詳細を見る

• The surface activities of mixed surfactants of partially-quaternized 2-vinylpyridine telomers (xRn-2VPQ, x is the total number of alkyl chains, n is the alkyl chain length) and monomeric alkyltrimethylammonium bromide (1RnQ) or gemini 1, 2-bis (alkyldimethylammonio) ethane dibromide (2RnenQ) were investigated at pH 2 by surface tension, foaming property, interfacial tension and emulsification power. The mixed critical micelle concentrations (cmcs) were intermediate between the pure component xRn-2VPQ and 1RnQ or 2RnenQ. xRn-2VPQ/2RnenQ system was higher efficiencies in lowering the surface tension than xRn-2VPQ/1RnQ. The surface tension was influenced by the alkyl chain length of binary surfactants and the mole fraction (α) of xRn-2VPQ. In particular, 2.0R10-2VPQ/2R10enQ system with α = 0.50 showed the lowest surface tension. The mixtures of two cationic multialkylated surfactants improved the foaming properties as compared with the pure component cationic surfactants. The similar trends in the surface tension and the foaming properties were observed for the lowering abilities of the interfacial tension at the water / toluene interface and emulsion stabilities.

• 日本油化学会の論文
• 2002-04-01

著者

• SHOSENJI Hideto

  Department of Applied Chemistry and Biochemistry, Graduate School of Science and Technology, Kumamot

• KOIDE Yoshifumi

  Department of Applied Chemistry, Faculty of Engineering, Kumamoto University

• Koide Y

  Department Of Applied Chemistry And Biochemistry Faculty Of Engineering Kumamoto University

• ESUMI Kunio

  Department of Applied Chemistry and Institute of Colloid and Interface Science, Science University o

• Shosenji Hideto

  Department Of Applied Chemistry And Biochemistry Faculty Of Engineering Kumamoto University

• Koide Yoshifumi

  Department Of Applied Chemistry And Biochemistry Faculty Of Engineering Kumamoto University

• YOSHIMURA Tomokazu

  Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University

• KAWASHIMA Kosuke

  Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University

• Esumi K

  Department Of Applied Chemistry And Institute Of Colloid And Interface Science Science University Of

• Esumi Kunio

  Department Of Applied Chemistry And Institute Of Colloid And Interface Science Science University Of

• Kawashima Kosuke

  Department Of Applied Chemistry And Biochemistry Faculty Of Engineering Kumamoto University

• Yoshimura Tomokazu

  Department Of Applied Chemistry And Biochemistry Faculty Of Engineering Kumamoto University

関連論文

• Novel Effects of Twin-tailed Cationic Surfactants on the Formation of Gold Nanorods
• Flotation of Uranium from Seawater with Phosphate Esters of C-Undecylcalix[4]resorcinarene
• Emulsification of Calix[4]arenes Bearing Four Chains and Transportation of Cesium Ion through Liquid Surfactant-Membrane
• 四側鎖型カリックス[4]レゾルシンアレンのリン酸エステルによる可溶化
• Structural Control of Three-dimensional Assemblies of Anisotropic Gold Nanoparticles Based on Their Different Shapes
• Preparation and Surface-Active Properties of N-Alkyl Maleamic Acid Telomer Type Surfactants Having Several Hydrocarbon Chains
• Surface Activities of Mixtures of Partially-Quaternized 2-Vinylpyridine Telomers and Cationic Gemini Surfactant
• Preparation and Surface Activities of Zwitterionic Surfactants Derived from Cotelomers of 4-Vinylpyridine and Methyl Acrylate
• Preparation and Surface-Active Properties of Complexanetype Trimeric Surfactants from Tris(2-aminoethyl)amine
• Preparation and Surface Activities of Cotelomers of Acrylic Acid and η-Octyl, 2-Ethylhexyl or 2-Phenylethyl Acrylate
• 2,3本のアルキル鎖を持ったコンプレキサン型界面活性剤の合成と界面化学的性質
• アクリル酸とアクリル酸n-ヘキシル,2-エチルヘキシルおよびn-ドデシルコテロマーの合成と多鎖型界面活性剤としての性質
• 重要度4〜6の2-ビニルピリジンテロマー系多鎖型界面活性剤の界面化学的特性
• Adsorption of Metal Ions to Surface-Template Resins Prepared with Amphiphilic Styrene Monomers Bearing Amino Carboxylic Acid
• Selective Adsorption of Metal Ions to Surface-Template Resins Prepared by Emulsion Polymerization Using 10-(p-Vinylphenyl)decanoic Acid
• Adsolubilization of Yellow OB and Parsol in Dioctadecyldimethylammonium Chloride Layer on Silica
• 界面活性剤吸着層を用いての粒子へのポリマ-コ-ティング〔英文〕
• The Effect of Functional Groups of Polymers on Dispersion of TiO2 in Nonpolar Solvent (目黒謙次郎教授追悼論文-1-)
• Adsolubilization of 2-Naphthol into Polymer-Surfactant Adsorbed Layer on Alumina
• Adsorption of Poly (styrenesulfonate) and Cationic Fluorocarbon Surfactant from their Mixed Solutions on Particles
• Adsorption of Cationic Monomeric and Gemini Surfactants on Montmorillonite and Adsolubilization of Vitamin E
• Species Differences in Oral Bioavailability of Methotrexate between Rats and Monkeys
• Preparation of Ultrafine Metal Particles in Ethanol Using a Photoinitiator
• 界面活性剤-水系でのUV照射による棒状金粒子の調製〔英文〕
• Preparation of Monodispersed Concentrated Gold Hydrosols from AuCl_4^--Cationic Surfactant Complexes
• Adsorption of a Single- or a Double-Chained Anionic Surfactant and Poly(vinylpyrrolidone) on Alumina from Their Binary Mixtures
• Fabrication of Nano-Patterns Composed of Metal Nanoparticles with Photo-Nanoimprint
• Study of the behavior of "uptake and release" of oxygen into perfluorocarbon-water emulsions.
• The thermodynamics of the micelle formation of sodium .ALPHA.,.OMEGA.-alkanediyl disulfate.
• Studies of collectors. V. The preparation of amidoxime-type surfactants and the flotation of a trace amount of uranium.
• A Study on Restricted Rotation in 1-Acylpyrroles
• Surface treatment of meso-carbon microbeads by oxygen plasma.
• Wetting of coal by nonionic surfactant and mixtures of nonionic and anionic surfactants.
• Adsorption of surface active agents on coals.
• Wetting of coal by aqueous surfactant solutions.
• Studies on special type surfactants. XVI Preparation of telomer-type surfactants containing 4-vinylpyridine and oxidative polymerization of 2,6-xylenol using their copper complexes.
• Study of the mixed solutions of an anionic and a nonionic surfactant by using the azo-hydrazone tautomerism of an acidic dye.
• The preparation of organo colloidal precious metal particles.
• Adsorption of tetrachloro-p-benzoquinone from various solvents on metal oxides.
• The interaction of pigment with polystyrene latex particles prepared using an amino-acid-type amphoteric emulsifier.
• Surface treatment of inorganic pigments by N.EPSILON.-acyllysine.
• Adsorption of electron acceptors on titania.
• Adsorption of oligomer type surfactants on iron oxide.
• The preparation of colloidal precious metal particles using copolymers of vinyl alcohol-N-vinylpyrrolidone.
• The regulation of emulsion polymerization of styrene with anionic-nonionic emulsifier mixtures.
• Physicochemical properties of eicosane-1,20-bis(trimethylammonium) dibromide in aqueous solution.
• Flocculation of iron(III) oxide hydrate sols induced by .ALPHA.,.OMEGA.-type surfactants.
• Studies of collectors. VII. Flotation of heavy metal ions by using colored surfactant.
• Physicochemical properties of .ALPHA.,.OMEGA.-type surfactant in aqueous solution. Bis(triethylammonium)1,20-eicosanediyl disulfate.
• The effect of ultraviolet radiation on wettability of silane coupling agents coated on glass.
• Zeta potentials of metal oxides coated with titanate coupling agents in aqueous solution.
• Mixed surfactant bilayers on monodispersed ferric hydro sols.
• Interaction between disodium 1,14-tetradecanediyl disulfate and sodium dodecyl sulfate or poly(oxyethylene) nony phenyl ether on alumina.
• The electron-donor property of zirconia.
• Effects of surfactants and surface treatment on aqueous dispersion of silicon carbide.
• Mixed colloidal dispersions of silica and hematite.
• The effect of ultraviolet radiation on the wettability of silicone polymers.
• Zeta potentials of metal oxide surfaces modified with silane coupling agents.
• The effect of ultraviolet radiation on wettability of polymer surfaces.
• Aqueous dispersion of iron oxide by acrylic oligomer surfactants.
• Zeta potentials of metal oxides in aqueous solution of water-soluble titanate coupling agents.
• Photochemical addition reactions of methanol and ethanol to 1,4-diaminoanthraquinone.
• The effect of surfactant on formation of calcium carbonate.
• Studies of collectors. X. Complexing ability of amino hydroxamic acid ligands with dioxouranium(VI) in aqueous solution.

もっと見る 閉じる

スポンサーリンク