Adsolubilization behavior of dyes caused by mixed surfactant bilayers formed on alumina.
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The adsolubilization of dyes (yellow OB and azobenzene) was performed on mixed bilayers consisting of anionic and nonionic surfactants formed on α-alumina. The adsolubilization capacity of the two dyes increased with the increase in the concentration of the dyes solubilized in the supernatant. The mixed bilayer consisting of anionic hydrocarbon (lithium dodecyl sulfate) and nonionic hydrocarbon surfactants (polyoxyethylene nonylphenyl ether) showed a greater adsolubilization capacity than that consisting of anionic fluorocarbon (lithium perfluorooctanesulfonate) and nonionic hydrocarbon surfactants. Further, the adsolubilization capacity of the dyes was affected by the oxyethylene chain length of the nonionic hydrocarbon surfactant in the mixed bilayer.
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