Temperature effect on the adsorption and micelle formation of aqueous dodecyltrimethylammonium chloride-hexane system.
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概要
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The adsorption at water/hexane interface and micelle formation of dodecyltrimethylammonium chloride (DTAC) were studied by measuring its interfacial tension as a function of temperature under atmospheric pressure at various concentrations around the critical micelle concentration (cmc). By applying the thermodynamic equations developed previously, the entropy and energy changes associated with the adsorption from monomeric and micellar states were estimated and compared with those of the DTAC solution–air system. It was found that the entropy and energy of the adsorbed film of DTAC are remarkably depressed by the coexistent hexane phase. This finding explains the positive entropy change associated with the adsorption of DTAC at water/air interface.
- 公益社団法人 日本化学会の論文
著者
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Kajiwara Ichiro
Department of Cardiovascualr Medicine, Kumamoto National Hospital
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Aratono Makoto
Department Of Chemistry Faculty Of Sciences Kyushu University
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Motomura Kinsi
Department Of Chemistry Faculty Of Science Kyushu University
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Abe Koji
Department Of Applied Chemistry Graduate School Of Engineering Tohoku University
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Ikeda Norihiro
Department Of Environmental Science Faculty Of Human Environmental Science Fukuoka Women's Univ
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Kajiwara Ichiro
Department of Chemistry, Faculty of Science, Kyushu University 33
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Ikeda Norihiro
Department of Chemistry, Faculty of Science, Kyushu University 33
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