Adsorption at water/air interface and micelle formation of decylammonium bromide and decylammonium chloride mixture.
スポンサーリンク
概要
- 論文の詳細を見る
The surface tension of the aqueous solution of decylammonium bromide (DeAB) and decylammonium chloride (DeAC) mixture was measured as a function of the total molality and composition of surfactants at 298.15 K under atmospheric pressure. By applying the thermodynamic equations derived previously to the experimental results, the compositions in the mixed adsorbed film and mixed micelle were evaluated. It was found that the adsorbed film and micelle are rich in DeAB, which is more surface active than DeAC, compared with the aqueous solution. Further, the DeAB and DeAC molecules were concluded to mix ideally in the states of the adsorbed film and micelle. On the other hand, the compositions were compared with those of dodecylammonium chloride (DAC)–DeAC mixture at the critical micelle concentration (cmc). The discrepancy between the compositions was proved to be related closely to the differences between the cmc's and between the surface tension values at the cmc of pure surfactants.
- 公益社団法人 日本化学会の論文
著者
-
Matsuki Hitoshi
Department Of Biological Science And Technology
-
Aratono Makoto
Department Of Chemistry Faculty Of Sciences Kyushu University
-
Motomura Kinsi
Department Of Chemistry Faculty Of Science Kyushu University
-
Ando Naoko
Department of Chemistry, Faculty of Science, Kyushu University 33
関連論文
- First-Order Wetting Transition and Line Tension of Hexadecane Lens at Air/Water Interface Assisted by Surfactant Adsorption
- Cholesterol Suppresses Pressure-induced Interdigitation of Dipalmitoylphosphatidylcholine Bilayer Membrane
- Barotropic Phase Transitions of 1-Palmitoyl-2-stearoylphosphatidylcholine Bilayer Membrane
- Effects of Pressure and Ethanol on the Phase Behavior of Dipalmitoylphosphatidylcholine Multilamellar Vesicles
- Adsorption of 1-Decyl-3-methylimidazolium Bromide and Solvation Structure of Bromide at the Air/Water Interface
- THERMODYNAMICS OF ANESTHETIC EFFECT ON THE PHASE TRANSITIONS OF LIPID MEMBRANES
- SURFACE ADSORPTION AND VOLUME BEHAVIOR OF LOCAL ANESTHETICS
- 2P302 Partition Coefficient of a Local Anesthetic into Model Biomembranes with Cholesterol-induced Domain Structure(40. Membrane structure,Poster Session,Abstract,Meeting Program of EABS & BSJ 2006)
- Effect of a Local Anesthetic Lidocaine Hydrochloride on the Bilayer Structure of Phospholipids
- Adsorption-Equilibrium Surface Tension of Surfactant Solutions ; Examination by the Drop Volume Method
- 2P129 Binding of Local Anesthetics to Bovine Serum Albumin(31. Protein folding and misfolding (II),Poster Session,Abstract,Meeting Program of EABS & BSJ 2006)
- A critical role for highly conserved Glu^ residue of oligopeptidase B from Trypanosoma brucei in thermal stability
- Effect of Counterions on the Surface Adsorption and Volume Behavior of Micelle-Forming Local Anesthetics
- EFFECT OF PRESSURE ON THE COLLOIDAL SOLUTION BEHAVIOR OF AQUEOUS LOCAL ANESTHETIC TETRACAINE SOLUTIONS
- Differential scanning calorimetric study on the Krafft phenomenon of local anesthetics
- Effect of Pressure on the Phase Behavior of Diheptadecanoylphosphatidylcholine Bilayer Membrane
- Surface Tension Measurements with High Accuracy: Investigation of Accuracy for Automatic Measurements by the Drop Volume Method〔和文〕
- Enthalpies of Adsorption and Micelle Formation of Octyl Methyl Sulfoxide
- VOLUME STUDY ON THE MICELLE FORMATION OF LOCAL ANESTHETIC DIBUCAINE HYDROCHLORIDE AND DODECYLTRIMETHYLAMMONIUM CHLORIDE MIXTURES
- EFFECT OF COUNTERIONS ON THE SURFACE ADSORPTION AND VOLUME BEHAVIOR OF MICELLE-FORMING LOCAL ANESTHETICS
- Volume Study on the Micelle Formation of Local Anesthetic Dibucaine Hydrochloride and Dodecyltrimethylammonium Chloride Mixtures
- BAROTROPIC Phase Transitions and Pressure-induced Interdigitation on Bilayer Membrane of Dimyristoylphosphatidylcholine
- Morphological Change of Vesicle Particles Can Produce a Peculiar Stepwise Transition in Dipalmitoylphosphatidylglycerol Bilayer at High NaCl Concentration
- Imaging of Phosphatidylcholine Bilayers by a High-Pressure Fluorescence Technique : Detection of the Packing Difference
- Thin-Thick Transition of Foam Film Driven by Phase Transition of Surfactant-Alkane Mixed Adsorbed Film
- Dynamics of Condensed Monolayer and Multilayer Formation of Hexadecylpyridinium Chloride-Sodium Dodecyl Sulfate Mixed Systems at the Air/Water Interface
- Thermotropic Phase Behavior of Binary Bilayer Membrane of Dipalmitoylphosphatidylcholine and Ergosterol
- Conformation of Adsorbed Polymeric Chain. III
- Thermotropic Phase Behavior of Hydrogenated Soybean Phosphatidylcholine–Cholesterol Binary Liposome Membrane
- Conformation of Adsorbed Polymeric Chain. IV
- Thermodynamic study on the adsorption of 1-octadecanol at hexane/water interface.
- Mixed monolayers of long normal-chain fatty acids with long normal alkyl esters. III. Pentadecanoic acid-esters system.
- Mixed monolayers of long normal chain fatty acids with long normal chain fatty alcohols.
- Effect of pressure on interfacial tension between oil and water.
- Thermodynamic study on the adsorption of dioctadecyl ether at hexane/water interface.
- Mixed monolayers of long normal chain fatty acids with long normal chain esters. II. Fatty acids-hexadecyl acetate system.
- Miexd monolayers of long normal chain fatty acids with long normal chain esters. I. Fatty acids-ethyl hexadecanoate system.
- Temperature effect on the adsorption and micelle formation of aqueous dodecyltrimethylammonium chloride-hexane system.
- Surface adsorption and micelle formation of dodecyltrimethylammonium chloride and decylammonium chloride mixture.
- Mixed Adsorbed Film and Micelles of Sodium Taurocholate and Sodium Taurodeoxycholate.
- Solvent effect on the adsorption of 1-octadecanol at oil/water interface.
- Equilibrium spreading pressure of the mixed system of normal long chain fatty acids.
- Thermodynamic study on penetration of pentadecanoic acid monolayer by dodecylammonium chloride.
- Effect of pressure on the adsorption of 1-octadecanol at oil/water interfaces.
- Effect of pressure on the adsorption and micelle formation of aqueous dodecyltrimethylammonium chloride-cyclohexane system.
- Ultralow interfacial tension in the vicinity of the upper critical solution temperature of the mixture of water and isobutyric acid.
- Adsorption of dodecyltrimethylammonium chloride from the micellar solution at water/air interface.
- Adsorption at water/air interface and micelle formation of decylammonium bromide and decylammonium chloride mixture.
- Negative azeotropic transformation in mixed monolayers of octadecylammonium chloride and tetradecanoic acid.
- Adsorption of cholesterol at hexane/water interface.
- X-ray Reflectivity Measurements for Freezing Transitions of Alkane Wetting Film on Surfactant Solution Surface
- 2P211 ジパルミトイルホスファチジルコリン二分子膜の熱的相挙動に及ぼすステロール効果(13A.生体膜・人工膜:構造・物性,ポスター,日本生物物理学会年会第51回(2013年度))